B1252

Sigma-Aldrich

Boron trifluoride-methanol solution

14% in methanol

Synonym(s):
Trifluoroborane
Linear Formula:
BF3 · MeOH
CAS Number:
Molecular Weight:
99.85
Beilstein/REAXYS Number:
3611499
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

assay

12-16% (NaOH, titration)

form

liquid

reaction suitability

reagent type: catalyst
core: boron

concentration

14% in methanol

density

0.859 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

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General description

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

Application

Used in the deactylation of acetanilides.It is also used to study the synthesis of amino group containing cyanine dyes of different types and to prepare fatty acid methyl esters.

Packaging

1 L in glass bottle
5, 100, 250, 500 mL in glass bottle
Bottle with screw-cap closure.

Signal Word

Danger

Supp Hazards

EUH014

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

F,T+

Risk Statement

11-14-24/25-26-35-39/23/24/25

Safety Statement

16-26-28-36/37/39-45

RIDADR

UN 3286 8(6.1)(3) / PGII

WGK Germany

WGK 2

Flash Point(F)

49.5 °F

Flash Point(C)

9.7 °C

Boron trifluoride-methanol complex-mild and powerful reagent for deprotection of labile acetylated amines.
Tetrahedron Letters, 44(11), 2301-2303 (2003)
Martin Trépanier et al.
Applied and environmental microbiology, 71(9), 5341-5347 (2005-09-10)
Lipids are the major form of carbon storage in arbuscular-mycorrhizal fungi. We studied fatty acid synthesis by Glomus intraradices and Gigaspora rosea. [(14)C]Acetate and [(14)C]sucrose were incorporated into a synthetic culture medium to test fatty acid synthetic ability in germinating...
Deacylation of N-Acetylated Amines with Alcohol and Boron Trifluoride.
Acta Chemica Scandinavica, 8, 529-530 (1954)
Sanjeet Mehariya et al.
Molecules (Basel, Switzerland), 24(7) (2019-04-17)
Lutein has several benefits for human health, playing an important role in the prevention of age-related macular degeneration (AMD), cataracts, amelioration of the first stages of atherosclerosis, and some types of cancer. In this work, the Scenedesmus almeriensis microalga was...
Antonio Molino et al.
Marine drugs, 17(2) (2019-03-01)
This research shows that carbon dioxide supercritical fluid (CO₂-SF) is an emerging technology for the extraction of high interest compounds for applications in the manufacturing of pharmaceuticals, nutraceuticals, and cosmetics from microalgae. The purpose of this study is to recover...

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